SYGEF(PVDF) - Product Range

GF Piping Systems Product Range International 2016 PVDF SYGEF

Introduction The best choice for you Corrosion and chemical resistant system solutions Georg Fischer Georg Fischer focuses on three core businesses: • Microelectronics GF Piping Systems, GF Automotive and GF Machining • Marine Solutions. The industrial corporation founded in 1802 • Water & Gas Utilities headquarters in Switzerland and operates approximately • Water Treatment 130 companies with more than 14 000 employees across 30 countries. GF Piping Systems is a leading supplier of plastic and metal Global presence piping systems with global market presence. For the Our global presence ensures customer proximity worldwide. treatment and distribution of water and chemicals, as well Sales companies in over 26 countries and representatives in as the safe transport of liquids and gases in industry, we another 80 countries provide customer service around the have the corresponding jointing technologies, fittings, clock. With 48 production sites in Europe, Asia and the USA valves, automation products and pipes in our portfolio. we are close to our customers and comply with local standards. A modern logistics concept with local distribution centers ensures highest product availability and short delivery times. GF Piping Systems specialists are always close by. Complete solutions provider Our extensive product range represents a unique form of product and competence bundling. With over 60 000 products, allied with a broad range of services, we offer individual and comprehensive system solutions for a variety of industrial applications. Our automation offering perfectly fits into our complete system approach and is thus GF Piping Systems headquarters in Schaffhausen, Switzerland. an integral part of our portfolio. Having the profitability of the project in focus, we optimize processes and applications that are integrated into the whole system. Our market segments Continually setting standards in the market, we directly Being a strong partner, GF Piping Systems supports its provide our customers with technological advantages. Due customers in every phase of the project. No matter which to our worldwide network customers benefit directly from processes and applications are planned in the following over 50 years of experience in plastics. market segments: • Building Technology From start to finish, we support our customers as a • Chemical Process Industry competent, reliable and experienced partner, actively • Energy contributing the know-how of an industrial company that has • Food & Beverage / Cooling been successful in the market for over 200 years.

The system The System for Highly Demanding Applications Superior purity, outstanding chemical and temperature resistance We are dedicated to designing, manufacturing and marketing piping systems for the safe and secure treatment or conveyance of diff erent qualities of water, liquids and chemicals. Customers rely on our 40+ years experience in Fluoro- polymers, our state-of-the-art production technology and our global presence with a worldwide service and training off ering. In close collaboration with end-customers and based on their high requirements, GF Piping Systems introduced the SYGEF family – specifi ed PVDF system based on certifi ed raw material. SYGEF is the optimal choice for highly demanding applications on the industrial fi eld. Individuality – From the planning stage to installation SYGEF Standard (PVDF) The single-bagged and reliable transport solution for chemical and water applications – even at high tempera- tures. Defi ned manufacturing conditions and a high per- formance raw material ensure the suitability for harsh environments as encountered in disinfection and chemi- cal transport. SYGEF Plus (PVDF HP) Pipes Fittings Valves The double-bagged, high purity (HP) piping system off ers additional opportunities for highly demanding applica- Quality control and assurance tions like conveying hot ultrapure water (HUPW) for mi- SYGEF systems warrant 100 % traceability through our com- croelectronic industries. By manufacturing, cleaning and puter aided quality production, packaging and labeling from packing under cleanroom conditions up to ISO class 5 raw material to the end product. (100), SYGEF Plus achieves an excellent surface fi nish, superior leach out characteristics and stringent particle Temperature and chemical resistance control combined with high reliability and product life- SYGEF systems are reliable for diffi cult applications with time. high temperatures and aggressive chemicals. Through our service team we off er individual support to match your ma- terial requirements.

Main benefi ts Complete system range • One-stop-shopping • Including pipes, fi ttings, valves and automation • Proven jointing technologies • Worldwide service: customizing, machine rental pool, training and sales support • System lifetime warranty* Total plastic solution • Outstanding temperature range • Excellent chemical resistance and purity • Extremely smooth surface fi nish • Rouging- and corrosion-free • Excellent abrasion resistance • UV and weather resistant • No electric conductivity • Low thermal conductivity High purity application • Virgin raw materials • No additives, stabilizers or pigments • Outstanding leach-out values • Fully controlled clean room production • 100 % traceability and audited by an independent external company Technical documentation Our extensive expertise of more than 50 years is fully docu- mented in detail in our technical manuals, planning funda- mentals and application guides. Training courses and on-site training We off er a wide range of training courses that provide par- ticipants an excellent opportunity to gain confi dence in work- ing with our products and proven jointing technologies. Automation Jointing technology Customizing and training Online and mobile calculation tools Technical support Our numerous online and mobile calculation tools in many For any successful installation a good technical support is diff erent languages support our customers in confi guring the key factor. A team of experts is available for individual and commissioning automation products. assistance all around the world. CAD library Customizing The extensive CAD library is the most frequently used The focus of our worldwide located customizing teams is planning tool. Our online database comprises over 30 000 manufacturing custom parts for special systems. Standard- drawings as well as technical data for our customers. Many ized processes guarantee the highest level of quality. formats are available. * Detailed information regarding the warranty can be found under: www.gfps.com – Planning Fundamentals

Completely controlled process The SYGEF High Purity Chain 2 ManufacturingManufacturing of the SYGEF Plus prod- 4 ucts is done in a clean room class 7 (10 000) or better using completely con- trolled processes. During the complete production process the inner surface area of the pipes, fi ttings and valves are in contact with air up to class 5 (100). 1Raw material Quality controlSYGEF starts the journey with the high- 3 A very detailed and unique QS- est available quality raw materials. Our system has been implemented to suppliers provide analytical proof of ensure the highest level of compliance with the highest specifi ca- quality. It is directly linked to the tions for every shipment. Once the raw manufacturing of the complete materials enter our plant, GF performs SYGEF range and includes a extensive incoming goods inspection. 100 % inspection of every prod- This assures that only raw materials ful- uct to ensure maximum perfor- fi lling the strict requirements are re- mance including visual inspec- leased for production. tion, valve packaging and valve seat-tests.

The high purity chain Manufacturing a product that achieves the lowest possible levels of particle contamination, TOC, anionic and cationic is made up of six links. contamination, ultimate surface fi nish is the result of the rel- evant links. But it does not stop here. When the Each one plays its product leaves our state-of-the-art warehouse it is delivered important role to you in protective packaging. Finally the installation is supported by the most advanced and established welding technology in existence. This technology combined with years of installation training experience make the most of the product when it is installed. 4 Cleaning & packing Installation & Highest purity through consistent 6 services cleaning of all SYGEF Plus products is With broad selection of system specifi c achieved in clean rooms up to class 5 state-of-the-art welding equipment GF is (100), using 18MΩ pure water and spe- off ering proprietary IR welding technolo- cial cleaning devices. All products are gy up to d450mm. Enhanced by industry packaged under selected and strictly leading weld bead inspection the highest monitored process conditions to avoid quality and most reliable system is en- contamination. Pipes are capped and sured. Project support including design, all SYGEF Plus components are double installation training and worldwide lo- bagged with a high quality, certifi ed cated service centers completing clean bagging material. the high purity chain. 5 LogisticsSYGEF products are stored in a sepa- rate warehouse for pipes, fi ttings and valves with distribution centers located worldwide. To avoid damage of SYGEF pipes GF has designed special wooden boxes for storage and transportation. This ensures that the highest possible quality and safety during transportation to the customer is ensured.

High tech factory Ettenheim / Germany SYGEF Cleanroom Production All SYGEF components are manufactured in the world’s largest cleanroom factory for fl uoropolymer products in Ettenheim GF Piping Systems played a major role in establishing the relevant standards SEMI F40, F48 and F57 for polymer component testing. Due to long experience and continuous improvements SYGEF Plus pipes, fi ttings and valves are exceeding these requirements to increase our customers’ yield. SYGEF Plus products are strictly fulfi lling the strong requirements of the ITRS* roadmap in order to be prepared for upcom- ing, even more demanding processes in the future. Fully controlled environment Surface quality The SYGEF production area includes 5 600m2 cleanroom: Smooth surfaces are achieved due to special equipment de- 4 000m2 class 7 (10 000), 1 000m2 class 6 (1 000) and 600m2 sign, proper tooling material’s selection, mirror fi nish sur- class 5 (100) in operation. All cleanrooms are continuously face of inner cores and preventive maintenance schedule. monitored and audited internally and by external companies. Thereby for all SYGEF Plus products the inner surface The microbiological and specifi ed particle measurements roughness according SEMI F57 is surpassed. are fully documented with a unique quality assurance (QA) system. R Profi l Filter DIN 4768 (RC) Le=0.800 mm Ultrapure water plant 2.0 Cleaning and rinsing of components with water of impecca- ble quality assures a constantly high level of cleanliness. 0.0 (μm) SYGEF Plus products are subject to regular leach-out con- -2.0 trols. Elementary system impurities like metals, anions and Taster T1E Lt = 4.80 mm 4.80 TOC** are constantly monitored to exceed SEMI F57 require- ments to warrant the highest possible system performance Inner surface roughness measured at a SYGEF Plus T90° equal d250 in use. SDR33 / PN10

Process expertise Safe and reliable system Operating staff has in-depth process knowledge and over 40 Quality control is an integral part in every step of the high years of experience in manufacturing products under strictly purity chain. Therefore each SYGEF Plus component is 100 % controlled cleanroom conditions. With regular internal train- visually inspected, including overall cleanliness, surface ap- ings we ensure that our production team keeps always the pearance and imperfections in accordance to internal speci- highest performance and has the latest insights. All the in- fi cations. jection molding machines and extrusion lines are developed All mechanical testing takes place in matchless Swiss feder- by using the latest innovations and technologies. ally accredited lab facility and external certifi cated labs. To- gether with unsurpassed installation equipment GF Piping Quality Assurance Systems is superior regarding ovality, internal stress level The safe delivery to jobsite and traceability of the fi nished and warpage. These key factors are able to infl uence the product back to the raw material batch are ensured through weld strength which leads to a longer system lifetime and a completely controlled processes. All relevant data are ar- higher safety. chived in an internal QA database and electronically avail- able for statistical researches. * ITRS: International Technology Roadmap for Semiconductors ** TOC: Total Organic Carbon

System range More Than a System With a constant focus on maximum reliability and safety the SYGEF system assures a sustained high level of product quality and outstanding performance for high-end applications. By using certifi ed and completely controlled manufacturing processes the SYGEF products are manufac- tured according to all relevant specifi cations and these procedures are regularly audited and evaluated to achieve continuous improvement. Our customers can be assured that their needs are met or exceeded and that the products comply with all necessary standards. SYGEF Standard and SYGEF Plus system range Products d DN SDR PN 21 16 Pipes 33 10 Socket fusion fi ttings 16 Butt fusion fi ttings 21 16 (IR and BCF compatible) 33 10 16 Ball valves 10 16 upon request Diaphragm valves 10 Butterfl y valves 10 16 Check valves 10 Pressure regulating valves 10 Ventilating- and bleed valves 16 Automation Flanges Flange seal Pipe clips IR fusion machine BCF fusion machine Butt fusion machine* Socket fusion machine SYGEF Standard SYGEF Plus * Technically possible but not recommended for SYGEF Standard 10 16 15 20 20 25 25 32 32 40 40 50 50 63 65 75 80 90 100 110 100 125 125 140 150 160 200 200 200 225 250 250 250 280 300 315 350 355 400 400 450 450

System specifi cations Standards: SYGEF Standard SYGEF Plus Material PVDF virgin High Purity PVDF (PVDF-HP) Color opaque opaque Density ~1.78 g / cm3 (EN ISO 1183) ~1.78 g / cm3 (EN ISO 1183) Thermal expansion coeffi cient 0.12–0.18 mm / m K (DIN 53752) 0.12–0.18 mm / m K (DIN 53752) Thermal conductivity at 23 °C 0.19 W / m K (EN 12664) 0.19 W / m K (EN 12664) Yield stress at 23 °C > 50 N / mm2 (EN ISO 527) > 50 N / mm2 (EN ISO 527) Tensile E-modul at 23 °C > 1 700 N / mm2 (EN ISO 527/ASTM D790) ≥ 1 700 N / mm2 (ISO 527/ASTM D790) Charpy notched impact strength at 23 °C ≥ 8 kJ / m2 (EN ISO 179) ≥ 8 kJ / m2 (EN ISO 179) Dimensions d16–d315 in accordance to ISO 10931 d20–d450 in accordance to ISO 10931 Temperature rating from -20 °C to 140 °C (-4 °F to 284 °F) Production - Pipes: extruded - Pipes: extruded - Fittings: injection moulded / machined - Fittings / Valves: injection moulded / - Valves: injection moulded (additional oil machined free treated and paint compatible / silicon - Produced under clean room class free) 7 (10 000) conditions. Subsequent assembling, quality inspection and cleaning is carried out using 18 MΩ pure water under clean room class 5-6 (100 -1 000) conditions Surface fi nish Inner surface Ra < 0.5 μm (20μin) Inner surface (PN10/ SDR33): Compliant to Semi F57 for injection moulded and extruded d ≤ 225 Ra ≤ 0.2 µm (8µin) components d = 250 Ra ≤ 0.3 µm (12µin) d280–315 Ra ≤ 0.4 µm (16µin) d355–450 Ra ≤ 0.65 µm (26µin) for injection moulded and extruded components Internal stress Pipes: ≤ 2.5 N / mm2; stress relieved by thermal annealing during manufacturing Material and product approvals DIBt SEMI F57 FM-4910 listed cleanroom material FM-4910 listed cleanroom material FDA CFR 21 177.2510 DIBt USP 25 class VI (physiological non-toxic) FDA CFR 21 177.2510 ASME BPE USP 25 class VI (physiological non-toxic) ASME BPE Packing Pipes capped and multiple components Pipes capped and each component single bagged in a specifi ed bag double bagged in a specifi c inner bag and outer bag under clean room Class 6 (1 000) conditions Marking and labeling All components are embossed with a permanent identifi cation during the production process to ensure full traceability: - Brand name - Lot No. - Material - Product description - Dimensions - Article number - Pressure rating - Standard and approvals Approvals / Acceptance: ISPE I ASME BPE I FM-4910

Jointing methods Convincing Welding Technologies A diverse range of innovative and intelligent welding solutions is enriched with global training and service off erings As a pioneer in the fi eld, GF Piping Systems has always placed a very high priority on developing innova- tive jointing techniques to fulfi ll specifi c requirements and materials in use. Simplicity in application, chemical resistance, thermal stability and long-term weld strength are the key drivers in our jointing technologies. With a global jointing training program, international machine rental and a worldwide network of service centers, our customers benefi t from our expertise and practical experience. Welding technology Welding machine Joint cross-section Microscopy Socket fusion – the strong connection The fast and reliable solution to pro- duce heavy-duty connections, in the workshop or the fi eld. Butt fusion – the economical connection Economical and fl exible fusion espe- cially for larger diameters. From manual machines to full CNC control with traceability. IR-Plus (Infrared) fusion – the fast, clean connection Fast, repeatable and clean welds via non-contact heating. Full traceability of the welding process, with user guidance. BCF-Plus fusion – the smooth connection Bead and Crevice Free jointing with the highest weld factor, lowest stress and completely smooth fusion zone without any intrusions. For more information about training courses from GF Piping Systems please contact our local sales companies.

SYGEF system System up to d450 • Completely controlled processes Key from raw material to installation• Overall system reliability, purity and safety • Wide range of pipes, fi ttings, valves, Products automation and accessories• Stress reduced pipes • SEMI F57 conformity High purity union Specially • Special HP design with unique positioning of the sealing • Defi ned tightening for optimal deforming of the O-ring Designed • Crevice and dead space free to avoid bacterial growth • Full plastic design without metal parts • In accordance with ASME-BPE for You High purity diaphragm valves• Maintenance free during temperature cycles due to full plastic design • Maximized purity due to minimized dead legs and manufacturing in Continuous improvements and new develop- clean room class 5 (100) ments assure a maximum level of quality to our • Double fl ow rate compared to customers. The SYGEF Plus system off ers very other diaphragm valves unique key products which are specially de- signed by GF Piping Systems to fulfi ll even the Pressure regulating valves (PRV) highest requirements in segments like Micro- • Special HP-version with patented elasto- electronic, Energy and Chemical Process Indus- mer-free piston – no abrasion try. • Valve assembly without metal screws for safer operation • Compact and intelligent modular design • Easy maintenance through replaceable cartridge Automated IR welding machine • Advanced QA/QC technology and monitored jointing work • Minimized operator errors by automated welding process • Full horizontal freedom for complex installation • State-of-the-art, man-machine interface with user friendly touchscreen display Ultrasonic fl owmeter • Noninvasive clamp-on design enables contamination free fl ow measurement • Easy to retrofi t – minimum downtime • Real time monitoring • Clean solution – no contact with medium • Economic solution

Specifi cations Exceeding Your Standards of Quality Technical specifi cations with focus on pressure, temperature and high purity attributes Excellent pressure/temperature performance Sterilization / sanitization / cleaning SYGEF PVDF is a thermoplastic fl uoropolymer with a melting Due to its outstanding material properties, our SYGEF sys- point above 175 °C and a wide service temperature range tems are suitable for a broad range of sterilization or clean- from -20 °C to 140 °C. SYGEF systems are ideal for use in ing methods using steam, hot water, ozone and chemicals. aggressive chemical or ultrapure water systems since they are generally considered inert, have high strength and stiff - ness, and are readily weldable into system components. Pressure-temperature diagram T (°F) 2 32 62 92 122 152 182 212 242 272 302 17 240 16 SDR21, PN16 15 220 14 200 13 12 180 11 160 10 140 9 8 120 7 100 6 5 80 4 SDR33, PN10 60 3 40 2 1 20 0 0 -30 -20 -10 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 T (°C) P Permissible pressure in bar, psi C = 1.6 C = 2.0 (recommended by GF) T Temperature in ˚C (Celsius), ˚F (Fahrenheit) The pressure/ temperature curve based on medium water, operating temperature of 20°C, valid life time of 25 years and the design factor of C = 2.0 or C = 1.6 respectively More information regarding technical specifi cations can be found online in our planning fundamentals: www.gfps.com P (bar) P (psi)

Chemical resistance For Your Operational Safety Professional material technology Polyvinylidene fl uoride (PVDF) – a high quality material Chemical resistance at 20 °C Partially crystalline Amorphous Stainless steel (Applications can be very dependent on the concentration) thermoplastics thermoplastics 1.4401 1.4301 Media Chemicals PVDF PE PP PVC-U PVC-C 316 304 HNO < 25 % 3 + o o + + o o Oxidizing acids 25 % < HNO < 65 %3 + o - o + o o (HNO , H CrO , H CrO aqueous solution 3 2 4 2 4 + o o o o o o H SO , etc.) 2 4 H SO < 70% 2 4 + + + + + - - 70 % < H SO < 96 % 2 4 + - - + + - - HCl < 30 % + + + + + o - Non oxidizing acids HF < 40 % (HCl, HF, etc.) + + + + - o - 40 % < HF < 75 % + + + - - - - HCOOH < 25 % + + + + + o - Organic 25 % < HCOOH < tech. pure + + + + - o - (formic acid, acetic CH COOH < 50 % 3 + + + + + o - acid, citric acid, etc.) 50 % < CH COOH < tech. pure 3 + + + o - o - C H OH (COOH) 3 4 3 + + + + + o - Inorganic (NaOH, KOH, etc.) - + + + o + + Bases Organic (amine, imidazole, etc.) - + + o - o o Salts NaCl, FeCl , FeCl , CaCl , etc. 2 3 2 + + + + + o o Halogens Chlorine, bromine, iodine, (no fl uorine) o - - o o o - Aliphatic hydrocarbons + o o + o + + Fuels / oils Aromatic hydrocarbons + - - - - + + Chlorinated hydrocarbons o - - - - o o Ketones o + + - - + + Solvents Alcohols + + + o - + + Esters o o o - - + + Aldehydes - + + - - + + Phenols Phenol, Cresol, etc. + + + - - + - + resistant o conditionally resistant, please consult us - not resistant Please note: The above list is only intended as a guideline and does not replace an indepth review of material suitability for the particular application. The information is based on our experience and is state of the art. These data are general indicators only. In practice, however, other factors such as concentra- tion, pressure and jointing technology must also be taken into consideration. The technical data are not binding and are not expressly warranted characteristics of the goods. Please contact us for help in selecting the right materials.

The smarter way of automation Automation Made Easy A unique system-based approach that bundles and integrates competencies, knowledge, best-in-class resources and technologies With an innovative product portfolio in the fi eld of measurement, control and actuation devices, GF Piping Systems consistently follows its system approach. The complete solution combines measure- ment, control and actuation technology together with high quality piping systems and represents a unique form of product and competence bundling. The system-integrated devices that measure values such as temperature, pressure and fl ow delivering accuracy, productivity, reliability and safety to customers in a wide range of industries. Providing the entire range of automation technology from simple instrument panels to complex measurement installations, GF Piping Systems has not only the product resources and the technical expertise, but also the global service and support infrastructure needed to meet the high customer requirements. ck edba PID co e ntro itio n f ller os B s P atch alv e co V nt n o Cti on ectio urn s Mea n fi t e r ti zngs na ly A s Se nsor Actuators Pressure regulating Actu a ement s Transmitters mete r ara ulti -p M er ro ll l o tr nn Co o lla ti ta ns I

Applications As Versatile as Your Applications Leading applications enabled by safe and reliable systems adapted to fit the needs of highly demanding industries GF Piping Systems develops customized best-in-class solutions, aligned to the specific requirements of our customers in various sectors of industry, enabling profitable operation. With our system knowledge and product expertise, we support our customers during the planning process, the sus- tainable realization of the projects and provide valuable added services. Expertise in developing and producing piping systems, combined with profound industry and market knowledge, based on long- standing experience, makes GF Piping Systems an uniquely qualified and professional partner for our customers. Microelectronics Chemical process industry Ultrapure water (UPW) is the SYGEF is uniquely equipped to lifeblood of semiconductor wet provide a broad and versatile processing. SYGEF Plus system solution for the safe convey- manufactured out of PVDF high ance of aggressive chemicals in purity material added with lat- extreme conditions. The excel- est IR welding technology offers lent life span for temperatures an industrial benchmark solu- up to 140°C including UV- resis- tion with excellent leach-out tance even allows outside in- values and no rouging. stallation. Energy Water treatment High voltage direct current With noticeably better water (HVDC) transmission is used balance compared to steel, because of its efficiency with SYGEF enables the right water less power loss. Through its quality for any WT application thermal resistivity SYGEF sys- like drinking water, industrial tems are well suited to conduct effluent treatment or filling and the deionized water in cooling emptying of tanks which are re- systems to dissipate the gener- quired in manufacturing and ated heat. Custom solutions of- processing plants to store li- fered by GF Piping Systems. quid media. Food & beverage Pharmaceutical Lighter and corrosion-resistant Down to the lowest pH values compared to stainless steel the excellent chemical resis- SYGEF is ideal for the convey- tance of SYGEF provides a high- ance of food. With FDA conform quality and cost-effective alter- BCF-welding a smooth and reli- native even to high-performance able connection is warranted. stainless steel or Titanium al- Maintenance cycles and life- loys. With BCF welding purest time are maximized to achieve water conveyance, minimal mi- highest system efficiency. crobiological growth and endo- toxin risk is ensured.

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Table of contents SYGEF Standard 20 SYGEF Plus 280 System-Oriented Fusion Jointing Machines 356 Index 373 19

SYGEF Standard Piping systems in PVDF